Rare earth in catalytic converters improve their effectiveness
2016-10-08

Rare earth in catalytic converters improve their effectiveness

  • An automotive catalytic converter (autocat) transforms the primary pollutants in engine exhaust gases into non-toxic compounds.  It is called a 3-way catalyst because it achieves three different chemical reactions:

    1. Oxidizing carbon monoxide into non-harmful carbon dioxide
    2. Oxidizing complex unburned hydrocarbonates into carbon dioxide and water


    1. Converting oxides of nitrogen (NOx) with carbon monoxide into harmless nitrogen and carbon dioxide


The 3-way catalyst consists of a mixture of precious metals, zirconium and rare earth (mostly cerium) wash coated into a brick inserted in the vehicle's exhaust pipe.

This market segment has been growing steadily above 5% per annum in the past 10 years and is expected to continue to grow as emission control regulations around the world are strengthened.

Additional catalytic systems are being developed, especially for addressing the higher oxides of nitrogen (NOx) emissions by diesel cars (linked to their higher combustion temperature). One of the most promising technologies (called Lean Nox Trap) uses cerium as a major catalyst and is particularly suitable for compact diesel cars.

The Influence of Deposition Methods of Support Layer on Cordierite Substrate on the Characteristics of a MnO2–NiO–Co3O4 Ce0.2Zr0.8O2 Cordierite Three Way Catalyst.pdf

The Effect of Different Promoters (La2O3, CeO2, and ZrO2) on the Catalytic Activity of the Modified Vermiculite-Based Bimetallic NiCu EXVTM-SiO2 Catalyst in Methane Dry Reforming.pdf

The Application of Rare Earth Modified Zr-based.pdf

Linking the Electrical Conductivity and Non-Stoichiometry of Thin Film Ce1−xZrxO2−δ by a Resonant Nanobalance Approach.pdf

Interaction of Perchloroethylene with Cerium Oxide in Three-Way Catalysts.pdf

Effects of hydrogen peroxide co-precipitation and inert N2 atmosphere calcination on CeZrLaNd mixed oxides and the catalytic performance used on Pd supported three-way catalysts.pdf

Ethyl Acetate Abatement on Copper Catalysts Supported on Ceria Doped with Rare Earth Oxides..pdf

Cerium–zirconium mixed oxide nanostructures for diesel soot oxidation synthesis and effect of structure.pdf

Ceria–zirconia mixed oxides Synthetic methods.pdf

Catalytic Combustion of Methane over Pd-Modified La-Ce-Zr-Al Catalyst.pdf